Chemical weathering was investigated by collecting samples from five selected weathering profiles in a high elevation granitic
environment located in Seoul, Korea. The overall changes of chemistry and mineralogical textures were examined reflecting
weathering degrees of the samples, using polarization microscopy, X-ray diffraction (XRD), electron probe micro analysis (EPMA),
X-ray fluorescence spectroscopy (XRF), and inductively coupled plasma–mass spectroscopy (ICP–MS). The chemical distribution
in the weathering profiles shows that few trace elements are slightly immobile, whereas most major (particularly Ca and Na)
and trace elements are mobile from the beginning of the granite weathering. On the other hand, there were mineralogical changes
initiated from a plagioclase breakdown, which shows a characteristic circular dissolved pattern caused by a preferential leaching
of Ca cation along grain boundaries and zoning. The biotite in that region is also supposed to be sensitive to exterior environmental
condition and may be easily dissolved by acidic percolated water. As a result, it seems that some rock-forming minerals in
the granitic rock located in Seoul are significantly unstable due to the environmental condition of acidic rainfall and steep
slopes, where they are susceptible to be dissolved incongruently leading some elements to be highly depleted. 相似文献
In situ LAM-ICPMS U-Pb, Hf-isotope and trace-element analyses of zircon have been used to evaluate the relative contributions of juvenile mantle and crustal sources to the intrusive rocks of the mafic to intermediate, gold-poor Tuckers Igneous Complex (TIC), and the spatially and temporally related, felsic Mount Leyshon Igneous Complex (MLIC), which hosts a gold-rich porphyry system.
The TIC intrusions range in age from 304.2 ± 9.1 Ma to 288.5 ± 6.4 Ma, and the MLIC intrusions from 291.0 ± 4.8 Ma to 288 ± 6 Ma. Cross-cutting relationships define the intrusion sequence from oldest to youngest; Diorite, Monzodiorite, Mafic Granodiorite and Biotite Microgranite within the TIC; Early Dyke, Southern Porphyry and Late Dyke within the MLIC.
Zircons from the earliest rock type within each complex have a wide range in Hf (5.2 to 14.8 for the TIC Diorite, 2.0 to 12.4 for the MLIC Early Dykes) suggesting the mixing of juvenile and crustal magmas. This interpretation is supported by trace-element data that show the presence of two distinct zircon populations in the MLIC Early Dyke. The later intrusive rocks have narrower ranges in Hf (typically < 4 Hf units) and trace-element patterns of zircon. This homogeneity suggests derivation from magmas produced by further mixing and fractional crystallisation of the TIC Diorite and the MLIC Early Dyke magmas respectively. A greater crustal contribution to the gold-rich MLIC is inferred from the range of median Hf (3.2 to 4.5 for the MLIC, 5.4 to 8.7 for the TIC). We suggest that the MLIC was derived by melting of more felsic crustal rocks, and with less input from juvenile mantle, then the TIC; it was not derived by fractional crystallisation of an intermediate to mafic TIC-like magma. Modelling of Hf isotope data yields a mean model age of 1040 ± 10 Ma (at 176Lu/177Hf = 0.015) for the crustal component in both complexes.
Gold was precipitated in the MLIC Breccia during the emplacement of the Late Dykes. The isotopically homogenous nature of the Late Dykes suggests that no additional juvenile-mantle input was involved at the mineralisation stage. This supports a model in which gold and other metals were indigenous to the Late Dykes magma and were concentrated by magma differentiation and fluid-evolution processes. 相似文献
Rock coatings are frequent on natural rock outcrops and even more on stone surfaces of historical buildings and monuments. They are interesting as some of them have a protective effect against erosion. In the last 30 years, research on rock coatings has been performed separately on either buildings or natural outcrops. This paper studies and compares thin coatings found on granitic rock surfaces of historical buildings with coatings found on natural granite outcrops in a same climatic area (NW Spain) by analysing their surface and cross-sections. As rock surfaces of buildings have known age they can be used to assess rates of weathering and coating growth. This is the first comparative study of formation of coatings on natural and built surfaces in the same region. Both endogenous (rock characteristics) and exogenous factors (climatic conditions, air pollution) that could affect the coatings formation are considered to assess the origin and formation of coatings. X-Ray Diffraction (XRD) and X-Ray Fluorescence (XRF) analyses of the underlying rocks, XRD analyses of the coatings and Scanning Electron Microscopy (SEM) observations of surface and cross-sections of the coatings, performing Energy Dispersive Spectrometry (EDS) and X-ray maps, were carried out to establish their composition. Fieldwork and results indicate that natural outcrops are widely covered by biological coatings or coatings formed due to rock weathering, while coatings found on rock ashlars are highly variable with air pollution, other building materials, organic droppings and micro-environmental factors contributing to coatings on rock ashlars in a more significant way than substrate characteristics and exposure time. 相似文献
<正>Carbonatites are commonly related to the accumulation of economically valuable substances such as REE.Cu,and P.The debate over the origin of carbonatites and their relationship to associated silicate rocks has been ongoing for about 45 years.Worldwide,the rocks characteristically display more geochemical enrichments in Ba,Sr and REE than sedimentary carbonate rocks.However,carbonatite's geochemical features are disputed because of secondary mineral effects.Rock-forming carbonates from carbonatites at Qinling.Panxi region,and Bayan Obo in China show REE distribution patterns ranging from LREE enrichment to flat patterns.They are characterized by a Sr content more than 10 times higher than that of secondary carbonates.The coarse- and fine-grained dolomites from Bayan Obo H8 dolomite marbles also show similar high Sr abundance,indicating that they are of igneous origin.Some carbonates in Chinese carbonatites show REE(especially HREE) contents and distribution patterns similar to those of the whole rocks.These intrusive carbonatites display lower platinum group elements and stronger fractionation between Pt and Ir relative to high-Si extrusive carbonatite.This indicates that most intrusive carbonatites may be carbonate cumulates.Maoniuping and Daluxiang in Panxi region are large REE deposits.Hydrothermal fluorite ore veins occur outside of the carbonatite bodies and are emplaced in wallrock syenite.The fiuorite in Maoniuping has Sr and Nd isotopes similar to carbonatite.The Daluxiang fiuorite shows Sr and REE compositions different from those in Maoniuping.The difference is reflected by both the carbonatites and rock-forming carbonates,indicating that REE mineralization is related to carbonatites.The cumulate processes of carbonate minerals make fractionated fluids rich in volatiles and LREE as a result of low partition coefficients for REE between carbonate and carbonatite melt and an increase from LREE to HREE.The carbonatite-derived fluid has interacted with wallrock to form REE ore veins.The amount of carbonatite dykes occurring near the Bayan Obo orebodies may support the same mineralization model,i.e.that fluids evolved from the carbonatite dykes reacted with H8 dolomite marble,and thus the different REE and isotope compositions of coarse- and fine-grained dolomite may be related to reaction processes. 相似文献